Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Because the reduction potential for fluorine to fluoride is so high, +2.87 V, cobalt(III) fluoride is one of the few simple stable cobalt(III) compounds. EC Number 233-062-4. Interactive image; ChemSpider: 59593 ECHA InfoCard: 100.030.045: EC Number: 233-062-4; PubChem CID. Empirical Formula (Hill Notation) CoF 3.

[d] AgSbF 6 (20 mol %), pyr=N ‐pyrazolyl. Handling, Storage, and Precautions: normally prepared and used in situ immediately after preparation. Enter your email address below and we will send you your usernameIf the address matches an existing account you will receive an email with instructions to retrieve your usernameEnter your email address below. 1.

Deshalb wird der Reinstoff luftdicht verschlossen in Gefäßen aus Glas, Quarz oder Metall aufbewahrt. Because the reduction potential for fluorine to fluoride is so high, +2.87 V, cobalt(III) fluoride is one of the few simple stable cobalt(III) compounds. 2H 2 O — et très réactif, utilisé dans des réactions de fluoration [3], le produit étant le fluorure de cobalt(II) CoF 2 Obtention. Identifiers ; CAS Number. The formula is CoI3. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077 Göttingen, GermanyMild C−F/C−H functionalization at ambient temperature.Enter your email address below.Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Beringstraße 4, 53115 Bonn, GermanyPlease note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Structure, properties, spectra, suppliers and links for: cobalt(iii) fluoride, 10026-18-3. Preparative Methods: cobalt(III) fluoride is normally prepared by reaction of cobalt (II) fluoride with elemental Fluorine at 200–300 °C in a stirred reactor usually constructed of copper or nickel and is then reacted with organic substrates at 100–500 °C.

This is easily determined by looking at the ions. Get the latest public health information from CDC: https://www.coronavirus.gov. [b] Di‐substituted product (8 %) was also isolated. ), and the DFG (SPP 1807) is gratefully acknowledged.Enter your email address below and we will send you your usernameIf the address matches an existing account you will receive an email with instructions to retrieve your usernameAs a service to our authors and readers, this journal provides supporting information supplied by the authors. It is used to synthesize organofluorine compounds. 10026-18-3 54496-71-8 dihydrate; 3D model . Detailed experimental and computational mechanistic studies on the C−F/C−H functionalizations provided strong support for a facile C−F cleavage.Can't sign in? Any queries (other than missing content) should be directed to the corresponding author for the article.The authors declare no conflict of interest.Sustainable, cobalt‐catalyst enabled, synthetically significant C−F/C−H functionalizations were achieved with an ample substrate scope at an ambient temperature of 25 °C, thereby delivering perfluoroallylated heteroarenes. To even that out to make a neutral molecule, you need to add 3 more electrons, and in this case that would be 3 iodide (1-) anions. Consequently, cobalt(III) and chloride would result in the cobalt(III) being reduced to cobalt(II). Consequently, cobalt(III) and chloride would result in the cobalt(III) being reduced to cobalt(II). If you do not receive an email within 10 minutes, your email address may not be registered, and you may need to create a new Wiley Online Library account. [a] 50 °C.

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